小注:
Reagent for high yield, low racemisation peptide coupling[1], mild and efficient reagent for the preparation fo esters from carboxylic acids and alcohols[2]; for esterification of amino at low temperature[3], for use in formation of mixed phophonate diesters[4]. The carboxyphosphonium salts formed by reaction with carboxylic acids can be reduced with NaBH4, providing a mild method for reduction of acids to alcohols[5]. Promotes the reaction of aliphatic primary amines with CS2 to give isothiocyanates which can be isolated in high yield or reacted in situ with nucleophiles[6].
Ref:
- Tetrahedron Lett. 1219 (1975)
- Tetrahedron Lett. 36, 4253(1995)
- Tetrahedron Lett. 35, 5603(1994)
- J. Org. Chem., 60, 5214(1995)
- Tetrahedron Lett., 39, 3319(1988)
- J. Che. Soc., Chem. Commun., 1995(1995)
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