4-Dimethylaminopyridine(DMAP)
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CATALOG No.：40153
MSDS Name：4-Dimethylaminopyridine, 99%
Synonyms：DMAP
Company Identification: Shanghai Medpep Co., Ltd.
For information, Call: +86 21 65566949
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
MSDS Name: 4-Dimethylaminopyridine, 99%
Purity: 99% min.
CAS No：1122-58-3
Molecular Formula: C7H10N2
Molecular Weight: 122.17
SECTION 3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW：
HIGHLY TOXIC. IRRITANT.
TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM. G.I. TRACT. CENTRAL NERVOUS SYSTEM.
POTENTIAL HEALTH EFFECTS：
EYE:
MAY CAUSE EYE IRRITATION.
SKIN:
MILD SKIN IRRITANT. HIGHLY TOXIC BY SKIN CONTACT.
INGESTION:
TOXIC BY INGESTION
INHALATION:
MAY BE TOXIC BY INHALATION. MAY ALSO BE IRRITATING TO THE RESPIRATORY TRACT.
CHRONIC: NO INFORMATION FOUND
SECTION 4. FIRST-AID MEASURES
EYES:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 20 MINUTES. ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH FINGERS. GET IMMEDIATE MEDICAL ATTENTION IF IRRITATION PERSISTS, OR SYMPTOMS OF OVEREXPOSURE BECOME APPARENT.
SKIN：
IMMEDIATELY WASH SKIN WITH PLENTY OF WATER FOR AT LEAST 20 MINUTES, WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION ESPECIALLY, IF IRRITATION DEVELOPS, PERSISTS, OR SYMPTOMS OF OVEREXPOSURE BECOME APPARENT.
INGESTION:：
IF SWALLOWED, CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING UNLESS INSTRUCTED BY MEDICAL PERSONNEL. GET MEDICAL ATTENTION.
INHALATION：
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION OR GIVE OXYGEN BY TRAINED PERSONNEL. KEEP WARM. GET IMMEDIATE MEDICAL ATTENTION.
NOTES FOR PHYSICIAN
TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
SECTION 5. FIRE FIGHTING MEASURES
FIRE:：NO DATA.
FLASH POINT：124°C (255.2°F)
AUTOIGNITION TEMPERATURE: 420°C (788°F)
EXTINGUISHING MEDIA：USE DRY POWDER OR CARBON DIOXIDE WHEN FIGHTING A FIRE INVOLVING THIS MATERIAL; WATER EXTINGUISHERS ARE NOT RECOMMENDED.
GENERAL INFORMATION：AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND, NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SECTION 6. ACCIDENTAL RELEASE MEASURES
USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN SECTION 8.
SPILLS AND LEAKS: CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. SWEEP UP OR ABSORB MATERIAL, THEN PLACE INTO A SUITABLE CLEAN, DRY, CLOSED CONTAINE. AVOID GENERATING DUSTY CONDITIONS. REFER TO SECTION 13 FOR DISPOSAL REQUIREMENTS.
ENVIRONMENTAL PRECAUTIONS: NO DATA.
SECTION 7. HANDLING AND STORAGE
HANDLING：
THIS PRODUCT SHOULD BE HANDLED ONLY BY, OR UNDER THE CLOSE SUPERVISION OF, THOSE PROPERLY QUALIFIED IN THE HANDLING AND USE OF POTENTIALLY HAZARDOUS CHEMICALS, WHO SHOULD TAKE INTO ACCOUNT THE FIRE, HEALTH AND CHEMICAL HAZARD DATA. IT SHOULD ALWAYS BE HANDLED IN AN EFFICIENT FUME HOOD OR EQUIVALENT SYSTEM. THE USER SHOULD CONSIDER THAT THE TOXICOLOGICAL AND PHYSIOLOGICAL PROPERTIES OF MANY COMPOUNDS ARE NOT YET WELL DETERMINED AND THAT NEW HAZARDOUS PRODUCTS MAY ARISE FROM REACTIONS BETWEEN CHEMICALS. CARE SHOULD BE TAKEN TO PREVENT ANY CHEMICAL FROM COMING INTO CONTACT WITH THE SKIN OR EYES AND FROM CONTAMINATING PERSONAL CLOTHING.
STORAGE：
STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT AND INCOMPATIBLE SUBSTANCES. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
HYGIENE PRACTICES：
NO DATA.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS：
USE APPROPRIATE ENGINEERING CONTROL SUCH AS PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. WHERE SUCH SYSTEMS ARE NOT EFFECTIVE WEAR SUITABLE PERSONAL PROTECTIVE EQUIPMENT, WHICH PERFORMS SATISFACTORILY AND MEETS OSHA OR OTHER RECOGNIZED STANDARDS. CONSULT WITH LOCAL PROCEDURES FOR SELECTION, TRAINING, INSPECTION AND MAINTENANCE OF THE PERSONAL PROTECTIVE EQUIPMENT.
EYES：WEAR APPROPRIATE PROTECTIVE GLASSES OR SPLASH GOGGLES AS DESCRIBED BY 29 CFR 1910.133, OSHA EYE AND FACE PROTECTION REGULATION, OR THE EUROPEAN STANDARD EN 166.
SKIN AND CLOTHING:WEAR APPROPRIATE PROTECTIVE GLOVES AND CLOTHING TO PREVENT SKIN EXPOSURE. CONSULT GLOVE MANUFACTURERS FOR GLOVE PERMEABILITY DATA.
RESPIRATORS：A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN APPROPRIATE CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED TO AIRBORNE CONCENTRATIONS THAT ARE TYPICALLY WITHIN 10 TIMES THE EXPOSURE LIMIT. USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHAS 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATORS USE.
OTHER PROTECTIVE：
FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITY AND A SAFETY SHOWER.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE： WHITE CRYSTALL.
ODOR: FAINT, AMINE-LIKE
BOILING POINT：162 °C。
FREEZING / MELTING POINT：109-111 °C
DYNAMIC VISCOSITY: NOT AVAILABLE.
SOLUBILITY IN WATER： 76 g/L @ 25°C (77°F)
SPECIFIC GRAVITY / DENSITY： NOT AVAILABLE.
SECTION 10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: NOT AVAILABLE.
CONDITIONS TO AVOID： HIGH TEMPERATURES, FLAMES AND SPARKS.
INCOMPATIBILITY WITH OTHER MATERIALS：OXIDIZING AGENTS. STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS： NOT AVAILABLE.
HAZARDOUS POLYMERIZATION: HAS NOT BEEN REPORTED
SECTION 11. TOXICOLOGICAL INFORMATION
RTECS #: US9230000
EYE EFFECT：NO DATA REPORTED IN THE CITED REFERENCES AS OF THE REVISION DATE.
SKIN EFFECT：SKIN - RABBIT LD50: 90 MG/KG (SUPPLIER DATA)
INGESTION EFFECT：ORAL - RAT LD50: 250 MG/KG (RTECS); ORAL - RAT LD50: 140 MG/KG (SUPPLIER DATA); ORAL - MOUSE LDLO: 470 MG/KG (RTECS)
INHALATION EFFECT：NO DATA REPORTED IN THE CITED REFERENCES AS OF THE REVISION DATE
OTHER TOXICOLOGICAL INFORMATION: INTRAVENOUS - MOUSE LD50: 56MG/KG
SECTION 12. ECOLOGICAL INFORMATION
ECOTOXICITY: NO INFORMATION PROVIDED.
BIOACCUMULATION: NO INFORMATION PROVIDED.
BIODEGREDATION: NO INFORMATION PROVIDED.
ENVIRONMENTAL STABILITY: NO INFORMATION PROVIDED.
SECTION 13. DISPOSAL CONSIDERATIONS
CONSULT WITH THE LOCAL GOVERNMENT REGULATIONS.
SECTION 14. TRANSPORT INFORMATION
DOT PROPER SHIPPING NAME: TOXIC SOLIDS, ORGANIC, N.O.S. (4-Dimethylaminopyridine)
DOT HAZARD CLASS: 6.1
DOT IDENTIFICATION NO: UN2811
DOT PACKING GROUP:II
DOT LABEL TYPE: TOXIC SOLIDS
SECTION 15. REGULATORY INFORMATION
Chinese Governmental regulations。
SECTION 16. OTHER INFORMATION
LAST UPDATED：2006,2,19
THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. IN NO EVENT SHALL CII BE LIABLE FOR ANY CLAIMS, LOSSES, OR DAMAGES OF ANY THIRD PARTY OR FOR LOST PROFITS OR ANY SPECIAL, INDIRECT, INCIDENTAL, CONSEQUENTIAL OR EXEMPLARY DAMAGES, HOWSOEVER ARISING, EVEN IF CII HAS BEEN ADVISED OF THE POSSIBILITY OF SUCH DAMAGES.
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